I found on Hacker News a list of several of the best websites with videos and interviews of entrepreneurs and business related topics. The list did include the one that you found, intruders.tv. Here is a list of the webites for future reference:
- Entrepreneurial Thought Leaders
- Successful business people giving talks on all aspects of business
- Startup School
- Entrepreneurs giving talks on how to create and sustain a startup
- Intruders.tv
- Great interviews with tech entrepreneurs
- TalkingHeadTV
- Videos on how to improve various aspects of life in general
- TED
- Intelligent, intellectual talks on various topics
IdeaFLITE 